全文获取类型
收费全文 | 74307篇 |
免费 | 7933篇 |
国内免费 | 4796篇 |
专业分类
化学 | 28305篇 |
晶体学 | 1423篇 |
力学 | 13045篇 |
综合类 | 1124篇 |
数学 | 21191篇 |
物理学 | 21948篇 |
出版年
2023年 | 658篇 |
2022年 | 979篇 |
2021年 | 2094篇 |
2020年 | 1994篇 |
2019年 | 1784篇 |
2018年 | 1540篇 |
2017年 | 1871篇 |
2016年 | 2506篇 |
2015年 | 2351篇 |
2014年 | 3318篇 |
2013年 | 5474篇 |
2012年 | 3627篇 |
2011年 | 4238篇 |
2010年 | 3624篇 |
2009年 | 4500篇 |
2008年 | 4651篇 |
2007年 | 4932篇 |
2006年 | 4208篇 |
2005年 | 3303篇 |
2004年 | 2999篇 |
2003年 | 2915篇 |
2002年 | 2501篇 |
2001年 | 2359篇 |
2000年 | 1912篇 |
1999年 | 1603篇 |
1998年 | 1580篇 |
1997年 | 1240篇 |
1996年 | 1179篇 |
1995年 | 1113篇 |
1994年 | 1002篇 |
1993年 | 921篇 |
1992年 | 884篇 |
1991年 | 684篇 |
1990年 | 565篇 |
1989年 | 411篇 |
1988年 | 410篇 |
1987年 | 347篇 |
1986年 | 348篇 |
1985年 | 454篇 |
1984年 | 340篇 |
1983年 | 203篇 |
1982年 | 362篇 |
1981年 | 516篇 |
1980年 | 459篇 |
1979年 | 506篇 |
1978年 | 415篇 |
1977年 | 326篇 |
1976年 | 285篇 |
1974年 | 89篇 |
1973年 | 158篇 |
排序方式: 共有10000条查询结果,搜索用时 109 毫秒
101.
Pingyu Zhu Qilin Zheng Shichuan Xue Chao Wu Xinyao Yu Yang Wang Yingwen Liu Xiaogang Qiang Junjie Wu Ping Xu 《Frontiers of Physics》2020,15(6):61501
One of the most important multipartite entangled states, Greenberger–Horne–Zeilinger state (GHZ), serves as a fundamental resource for quantum foundation test, quantum communication and quantum computation. To increase the number of entangled particles, significant experimental efforts should been invested due to the complexity of optical setup and the difficulty in maintaining the coherence condition for high-fidelity GHZ state. Here, we propose an ultra-integrated scalable on-chip GHZ state generation scheme based on frequency combs. By designing several microrings pumped by different lasers, multiple partially overlapped quantum frequency combs are generated to supply as the basis for on-chip polarization-encoded GHZ state with each qubit occupying a certain spectral mode. Both even and odd numbers of GHZ states can be engineered with constant small number of integrated components and easily scaled up on the same chip by only adjusting one of the pump wavelengths. In addition, we give the on-chip design of projection measurement for characterizing GHZ states and show the reconfigurability of the state. Our proposal is rather simple and feasible within the existing fabrication technologies and we believe it will boost the development of multiphoton technologies. 相似文献
102.
炸药颗粒的点火燃烧过程一直是人们关注的热点问题。近年来,三维离散元技术在中尺度观测颗粒材料的动力学过程中拥有显著优势。炸药燃烧属于颗粒材料的反应动力学,运用三维离散元技术(DM3)可以有效地观测炸药燃烧传播的过程。以奥克托今(HMX)颗粒为例,本文成功模拟并观测到了HMX颗粒的燃烧反应程度,确定了颗粒开始燃烧反应的时间,以及燃烧反应传播的时间。同时,结合落锤冲击颗粒的三维图像以及其表观压强和放热功率,得到了HMX颗粒燃烧反应、燃烧传播的整个反应动力学过程,包括颗粒在冲击加载下碎化塑性变形的过程,颗粒燃烧反应放热的过程,落锤回弹颗粒喷射的过程等。同时,进一步说明了尖顶颗粒更利于颗粒点火,平顶颗粒有抑制颗粒点火的能力。 相似文献
103.
Chloride‐Selective Electrodes Based on “Two‐Wall” Aryl‐Extended Calix[4]Pyrroles: Combining Hydrogen Bonds and Anion–π Interactions to Achieve Optimum Performance 下载免费PDF全文
Jad Sabek Dr. Louis Adriaenssens Tomàs Guinovart Dr. Enrique J. Parra Prof. F. Xavier Rius Prof. Pablo Ballester Dr. Pascal Blondeau 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(1):448-454
The performance of chloride‐selective electrodes based on “two‐wall” aryl‐extended calix[4]pyrroles and multiwall carbon nanotubes is presented. The calix[4]pyrrole receptors bear two phenyl groups at opposite meso‐positions. When the meso‐phenyl groups are decorated with strong electron‐withdrawing substituents, attractive anion–π interactions may exist between the receptor’s aromatic walls and the sandwiched anion. These anion–π interactions are shown to significantly affect the selectivity of the electrodes. Calix[4]pyrrole, bearing a p‐nitro withdrawing group on each of the meso‐phenyl rings, afforded sensors that display anti‐Hofmeister behavior against the lipophilic salicylate and nitrate anions. Based on the experimental data, a series of principles that help in predicting the suitability of synthetic receptors for use as anion‐specific ionophores is discussed. Finally, the sensors deliver excellent results in the direct detection of chloride in bodily fluids. 相似文献
104.
Solubility and Crystallizability: Facile Access to Functionalized π‐Conjugated Compounds with Chlorendylimide Protecting Groups 下载免费PDF全文
Dr. Jan Gebers Damien Rolland Dr. Roman Marty Dr. Stéphane Suàrez Luca Cervini Dr. Rosario Scopelliti Dr. Jan Cornelius Brauer Prof. Dr. Holger Frauenrath 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(4):1542-1553
Functional π‐conjugated molecules are relevant for the preparation of new organic electronic materials with improved performance. However, their synthesis is often rendered difficult by their inherently low solubility, and the permanent attachment of solubilizing groups may change the properties of the material. Here, we introduced the chlorendylimidyl moiety as a new temporary protecting group for the straightforward large‐scale synthesis of protected quarter‐, sexi‐, octathiophene, and perylene bisimide diamine and dicarboxylic acid derivatives. The obtained chlorendylimides and chlorendylimidyl active esters were highly soluble in organic solvents, and optical spectroscopy confirmed the low tendency of the compounds to aggregate in solution. At the same time, they could be conveniently purified by recrystallization or precipitation. Single‐crystal X‐ray structures obtained for most compounds showed supramolecular motifs highlighting the role of the rigid, polychlorinated chlorendyl moieties in their crystallization. The obtained protected diamine and dicarboxylic acid derivatives were easily deprotected and converted into various amide‐substituted oligothiophenes and perylene bisimides that are of interest as new functional materials for organic electronic thin film or nanowire devices. 相似文献
105.
The analysis of vitamin D status, with special emphasis on 25-hydroxyvitamin D and 1,25-dihydroxyvitamin D, is gaining interest in clinical studies due to the classical and non-classical effects attributed to this prohormone. In this research, the influence of the two steps preceding determination (viz. sample collection and preparation) on the quantitative analysis of vitamin D and its more important metabolites has been studied. Two preparation approaches, deproteination and solid-phase extraction (SPE), have been evaluated in terms of sensitivity to delimit their application, thus establishing that detection of 1,25-dihydroxyvitamin D cannot be addressed by protein precipitation. Concerning sample collection, serum and plasma reported high accuracy (above 83.3%) for vitamin D and metabolites, while precision, expressed as relative standard deviation, was below 12.9% for all analytes in both samples. Statistical analysis revealed that serum and plasma provided similar physiological levels for vitamin D3, 24,25-dihydroxyvitamin D3 and 25-hydroxyvitamin D3, while significantly different levels were obtained for 1,25-dihydroxyvitamin D3, always higher in plasma than in serum. Sample collection and treatment have proved to be significant in the analysis of vitamin D and its relevant metabolites. 相似文献
106.
We give a sheaf theoretic interpretation of Potts models with external magnetic field, in terms of constructible sheaves and their Euler characteristics. We show that the polynomial countability question for the hypersurfaces defined by the vanishing of the partition function is affected by changes in the magnetic field: elementary examples suffice to see non-polynomially countable cases that become polynomially countable after a perturbation of the magnetic field. The same recursive formula for the Grothendieck classes, under edge-doubling operations, holds as in the case without magnetic field, but the closed formulae for specific examples like banana graphs differ in the presence of magnetic field. We give examples of computation of the Euler characteristic with compact support, for the set of real zeros, and find a similar exponential growth with the size of the graph. This can be viewed as a measure of topological and algorithmic complexity. We also consider the computational complexity question for evaluations of the polynomial, and show both tractable and NP-hard examples, using dynamic programming. 相似文献
107.
Jin-Zi Ding 《中国物理 B》2021,30(12):126201-126201
Flower-like tungsten disulfide (WS2) with a diameter of 5-10 μm is prepared by chemical vapor deposition (CVD). Scanning electron microscopy (SEM), energy dispersive spectrometer (EDS), Raman spectroscopy, and ultraviolet-visible (UV-vis) spectroscopy are used to characterize its morphological and optical properties, and its growth mechanism is discussed. The key factors for the formation of flower-like WS2 are determined. Firstly, the cooling process causes the generation of nucleation dislocations, and then the "leaf" growth of flower-like WS2 is achieved by increasing the temperature. 相似文献
108.
Dayang Yu Guoliang Mao Huaixun Cai Shuhua Wang Jiandang Liu Pengju Pan Yongzhong Bao 《Journal of polymer science. Part A, Polymer chemistry》2021,59(9):754-763
2,2-bistrifluoromethyl-4,5-difluoro-1,3-dioxole-co-tetrafluoroethylene (PDD-TFE) copolymer is a good candidate to prepare gas separation membranes with excellent permeability due to its free volume characteristics. However, the influence of PDD-TFE copolymer structure on its free volume characteristics is less studied. In this paper, PDD-TFE copolymers with different compositions and molecular weights were synthesized, and their free volume characteristics were analyzed by positron annihilation lifetime spectroscopy and a molecular dynamics simulation. It indicated that the molar fraction of PDD in copolymers had a significant effect on free volume characteristics, while the molecular weight of copolymers exerted a slight influence on free volume when the molecular weight exceeded a critical region (intrinsic viscosity [η] > 68 ml g−1). PDD-TFE copolymers with greater PDD molar fractions (i.e., 72% and 84%) showed bimodal distributions in positron lifetime and free volume size distributions, while PDD-TFE copolymers with lower PDD molar fractions (i.e., 27% and 35%) exhibited a single peak. The long-lifetime parameter τ3 was assigned to micro-cavities formed by [-(TFE)y-PDD-] segments and τ4 was attributed to micro-cavities formed by [-(PDD)x-TFE-] segments. The cis and trans transitions of PDD led to a local multilayer spiral structure with a 2.6–4.3 Å layer spacing, which would also increase the free volume of copolymers. 相似文献
109.
Savita Verma Deepak M. Maher Samadhan S. Nagane Bhausaheb V. Tawade Prakash P. Wadgaonkar 《Journal of polymer science. Part A, Polymer chemistry》2019,57(5):588-597
New aromatic (co)polyesters containing pendant propargyloxy groups were synthesized by phase transfer‐catalyzed interfacial polycondensation of 5‐(propargyloxy)isophthaloyl chloride (P‐IPC) and various compositions of P‐IPC and isophthaloyl chloride with bisphenol A. FTIR and NMR spectroscopic data, respectively, revealed successful incorporation of pendant propargyloxy groups into (co)polyesters and formation of (co)polyesters with desired compositions. (Co)polyesters exhibited good solubility in common organic solvents such as chloroform, dichloromethane, and tetrahydrofuran and could be cast into transparent, flexible, and tough films from chloroform solution. Inherent viscosities and number average molecular weights of (co)polyesters were in the range 0.77–1.33 dL/g and 43,600–118,000 g/mol, respectively, indicating the achievement of reasonably high‐molecular weights. The 10% weight loss temperatures of (co)polyesters were in the range 390–420 °C, demonstrating their good thermal stability. (Co)polyesters exhibited Tg in the range 146–170 °C and Tg values decreased with increase in mol % incorporation of P‐IPC. The study of non‐isothermal curing by DSC indicated thermal crosslinking of (co)polyesters via propargyloxy groups. The utility of pendant propargyloxy group was demonstrated by post‐modification of the selected copolyester with 1‐(4‐azidobutyl)pyrene, 9‐(azidomethyl)anthracene, and azido‐terminated poly(ethyleneglycol) monomethyl ether via copper(I)‐catalyzed Huisgen 1,3‐dipolar cycloaddition reaction. FTIR and 1H NMR spectra confirmed that click reaction was quantitative. © 2018 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2019 , 57, 588–597 相似文献
110.
Andrey A. Dobrynin 《Discrete Mathematics》2019,342(1):74-77
Distance between two vertices is the number of edges in a shortest path connecting them in a connected graph . The transmission of a vertex is the sum of distances from to all the other vertices of . If transmissions of all vertices are mutually distinct, then is a transmission irregular graph. It is known that almost no graphs are transmission irregular. Infinite families of transmission irregular trees of odd order were presented in Alizadeh and Klav?ar (2018). The following problem was posed in Alizadeh and Klav?ar (2018): do there exist infinite families of transmission irregular trees of even order? In this article, such a family is constructed. 相似文献